The multi-configurational time-dependent Hartree approach
Abstract
A new multi-configurational approach to the time-dependent Schrödinger equation is proposed. This approach leads to working equations which are particularly simple and transparent. It can be used for n degrees of freedom and for any choice of the number of configurations. The new approach is tested on a model of coupled oscillators showing fast convergence towards the exact results as the number of configurations is increased.
- Publication:
- Chemical Physics Letters
- Pub Date:
- January 1990
- DOI:
- Bibcode:
- 1990CPL...165...73M