The State of the LOD Cloud document provides statistics about commonly used vocabularies (October 2010)
Blog post listing the 100 most common RDF namespaces (August 2006)
The paper Ding, Finin: Characterizing the Semantic Web on the Web gives an overview about which vocabularies were used in May 2006.
There are several sites collecting RDF vocabularies and OWL ontologies. Try to reuse these before inventing something new.
Some vocabularies provide different URIs to describe equivalent (or more / less precise) resources. It seems important to define mappings (vocabulary links) between them.
The Web of Data contains large amounts of instance data with instances being partly interlinked between data sources. The instance data as well as the connections can be used to mine vocabulary mappings (vocabulary links) from the Web of Data. Existing work is this space is:
Microformats define schemata for embedding data into HTML pages. Data that is published using a microformat can be transformed to RDF using GRDDL. See Microformat FAQs for RDF Fans
This section collects poposals on which properties to use to set links between different entities.